Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium.

نویسندگان

  • Valeri Leich
  • Thomas P Spaniol
  • Laurent Maron
  • Jun Okuda
چکیده

Bis(triphenylsilyl)calcium [Ca(SiPh3)2(thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C-C double bonds efficiently and regioselectively.

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عنوان ژورنال:
  • Chemical communications

دوره 50 18  شماره 

صفحات  -

تاریخ انتشار 2014